Chile's verdant lakes region is a centre for dairy farming, with more than 9,000 cows and sheep.
People have also refused to leave Mantilhue, along the Rio Bueno, just six miles from the volcano eruption.
The plume of ash has caused the airport at Argentinian ski resort San Carlos de Bariloche to be closed.
The eruption, 575 miles south of the capital Santiago, has also seen a busy border crossing between the two countries shut.
There are four volcanoes in the chain, but it was unclear which one has erupted because of the ash cover and weather conditions. The chain last saw a major eruption in 1960.
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